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Russia's Luna-25 spacecraft crashes into Moon
(www.bbc.com)
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You're correct about the Appolo missions, but don't tell me the Space Race was about science. It's was fully politically motivated also. Without the Cold War nobody would have put the money and effort in so the Moon landing could happen in '69.
There are a lot of other missions that happened for pure scientific reasons but I don't think this is one of them.