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KDE Connect - connection across routers
(lemm.ee)
KDE is an international technology team creating user-friendly free and open source software for desktop and portable computing. KDE’s software runs on GNU/Linux, BSD and other operating systems, including Windows.
If you encounter a bug, proceed to https://bugs.kde.org, check whether it has been reported.
If it hasn't, report it yourself.
PLEASE THINK CAREFULLY BEFORE POSTING HERE.
Developers do not look for reports on social media, so they will not see it and all it does is clutter up the feed.
Or if OP really can't do that (that's by far the best solution), KDE Connect also lets you hardcode some IPs it'll try to connect to. Given the computer is on the main network, using the IP of the computer directly would make it work fine behind the second router.
But ideally, they really should be the same network.