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I've invented a 100% efficient combustion engine
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Furnace.
But even a furnace/fireplace is subject to incomplete combustion, where some portion of the wood is transformed into byproducts that rob some of the energy of the fire. There's actually a big difference in the amount of energy you can get out of a fire, depending on the type of stove that's used.
That's some of what NGOs have tried to do for developing countries - find cheap and easily produceabke stove designs that can reduce the amount of wood needed and improve air quality in the home.
Yes he is incorrect. NG furnace is 95% efficient iirc.