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(sh.itjust.works)
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Personally, I prefer the AMR or even the medium armor penetrating diligence, which can both kill a devastator in one headshot. The latter weapon is even a primary.
Railgun does it in a body shot. Not sure if it needs a charge, but I usually give it a 3 second unsafe charge anyway, because I am not good.
That's fair, as much as I love headshotting devastators, the railgun seems like it can deal with them a little more consistently, which is something at least.