Welcome! I use home-manager and sops-nix. Use flakes, always!
For neovim i use https://github.com/nix-community/nixvim, but i've been eyeing https://github.com/NotAShelf/nvf
For content i recommend Vimjoyer and the official NixOS wiki.
Personally i used this as a good base, to see how some things are done. But then i started doing my own thing eventually. https://github.com/Aylur/dotfiles. You can search on github for NIxOS configs to see how things are done, and you have this community to ask questions.
Have fun! If i find more resources i'll edit this comment.